SHAMPOO
FOR EXTERNAL USE ONLY
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✓ INTRODUCTION
✓ REQUIRMENT OF SHAMPOOS
✓ CLASSIFICATION
✓ TYPES OF SHAMPOOS
✓ MECHANISM
✓ COMPOSITION
✓ FORMULATION
✓ EVALUTION OF SHAMPOOS
✓ CONTAINER
✓ SPECIFIC EXAMPLES
✓ REFERENCES
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INTRODUCTION
• A Shampoo is a preparation of a surfactant ( i.e.
surface active material ) in a suitable from – liquids ,
solids or powder – which when used under the
specified conditions will remove surface grease , dirt
, & skin debris from the hair shaft & scalp without
affecting user.
• Some cases medicated shampoo ( anti dandruff )
prevent hair full
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REQUIRMENT OF SHAMPOOS
• It should effectively & completely remove dust or soli,
excessive sebum or other fatty substances & loose
corneal cells from the hair.
• It should produce a good amount of foam to satisfy
the psychological requirement of the user.
• It should be easily removed on rinsing with water.
• It should leave the hair non-dry , soft , lustrous with
good manageability & minimum fly away.
• It should be impart a pleasant fragnance to the hair.
• It should not cause any side-effects / irritation to skin
or eye.
• It should not make the hand rough & chapped.
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CLASSIFICATION
1.Soap base shampoo
2.Detergent base
shampoo
TYPES OF SHAMPOO
• Powder shampoo
• Liquid shampoo
• Lotion shampoo
• Cream shampoo
• Jelly shampoo
• Aerosol shampoo
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• Specialized shampoo
1. Conditioning shampoo
2. Anti – dandruff shampoo
3. Baby shampoo
4. Two layer shampoo
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MECHANISM
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COMPOSITION
• Surfactants are the main component of
shampoo . Mainly anionic surfactants are
used.
• The raw materials used in the manufactant of
shampoo are
1. PRINCIPAL OF SURFACTANT:
provide detergency & foam.
SLS , MLS
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2. SECONDARY SURFACTANTS :
improve detergency , foam & hair condition
mono alkali sulfo succinate , turkey oil
3. SOAP :
Na , k , soap
4. DETERGENT :
SLS , sulphated mono glycerine
5. CONDITIONING AGENT :
lanolin , mineral oil , amino acid , herbal
extracts , vegtable oil , egg derivatives
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6. FOAM BUILDERS :
Lauroyl monoethanolamide , sarcosinates.
7. VISCOSITY MODIFIERS :
❑ electrolytes = NH4CI , NaCl
❑ Natural gums = gum karaya , tragacanth ,
alainates .
❑ Cellulose derivatives = hydroxyl ethyl
cellulose, methyl cellulose .
❑ Carboxy vinyl polymers = carbopol 934
❑ Other = PVP, phosphate esters , CMC
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8. CLARIFYING AGENTS :
❑ solubilizing alcohol = ethanol , iso propanol
❑ Phosphate
❑ Non – ionic solubilizers = polyethoxylated
alcohol , esters.
9. PERFUMES :
herbal , fruit or floral fragnances.
10.PRESERVATIVES :
methyl & propyl paraben , HCHO ( most
effective )
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11. SOLUBILIZING AGENT :
alphatic alcohol , urea ( di amide )
12. CHELATING AGENT :
EDTA , sodium poly phosphate.
13. INORGANIC SALTS :
NaCl , ammonium phosphate , ammonium
chloride.
14. EMOLLIENT :
lanoline & derivative.
15.FEAM STABILIZER :
ethanol amide , F.fatty acid , amine oxide.
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16. PH MODIFIER :
5.6 to 6.2 = citric acid PH adjustments
17. FUNCTIONAL ADDITIVES :
Protein , amino acid ( glutamic acid ) ,
Ethylene oxide , dimethyl siloxane , silicone
derivatives .
18. ANTI DANDRUFF AGENT :
selenium sulfide , zinc pyrithone ( ZPT ) ,
Salicylic acid , neem oil , beta – napthol, ppt of
sulphate
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FORMULATION
1. POWDER SHAMPOO
senna powder = 5 %
soap water = 50 %
sodium carbonate = 22.5 %
potassium carbonate = 7.5 %
borax = 15 %
perfume = q.s
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2. LOTION SHAMPOO
TLS = 35 %
glyceryl monostearate = 2 %
magnesium stearate = 1 %
water = up to 100 %
color = q.s
perfume , preservatives = q.s
3. LIQUID SHAMPOO
SLS = 40 %
NaCl = 2 – 4 %
water = up to 100 %
perfume , color , preservative = q.s
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4. CREAM SHAMPOO
SLS = 38 %
cetyl alcohol = 7 %
water = up to 100 %
color , perfume = q.s
preservative = q.s
5. AEROSOL SHAMPOO
TLS = 60 %
coconut diethanolamide = 2 %
water = up to 90 %
propellent = 10 %
color , perfume , preservative = q.s
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6. JELLY SHAMPOOS
alkyl dimethyl benzalkonium Cl = 15 %
TLS ( 40 % ) = 28 %
Coconut ditethanolamide = 7 %
HPMC = 1 %
water = up to 100%
color , perfume , preservative = q.s
7. TWO LAYER SHAMPOO
SLS = 27 %
cocamidopropylamine oxide = 5 %
lauramine DEA = 1 %
lactic acid ( 50 % ) = 1 %
formaldehyde = 0.1 %
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8. BABY SHAMPOO
MLS ( 27.5 % ) = 11 %
cocamidopropyl betaine = 5 %
polysorbate 20 = 1 %
PEG 600 = 3.5 %
perfume , color , preservative = Q.S
citric acid = TO pH 6
water (deionized) ; aqua (INCI) = TO 100%
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9. ANTI – DANDRUFF SHAMPOO
F1 Thymol = 0.05 %
Menthol = 0.1 %
Camphor = 0.1 %
TLS = 55 %
Water = up to 100 %
color , perfume , preservation = q.s
F2 selenium sulfide = 2.5 %
bentonite = 5 %
SLS paste = 35 %
water = up to 100 %
color , p.fume , preservative = q.s
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PREPARATION AND EVALUATION OF
SOLID CREAM / GEL SHAMPOO
• COCOUNT OIL = 10ML
• OLIVE OIL = 4.7ML
• CASTOR OIL = 2ML
• KOH = 1.5GM
• GLYCEROL = 2.25ML
• PERFUME =Q.S
• CMC =Q.S
• WATER = Q.S
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PROCEDURE
• All the weighed contents able taken the solid
base will mixed throughly and liquid base
mixed separately these mixture were titurate
and mixing together to get a fine shampoo
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EVALUATION OF SHAMPOOS
1. Clarity
2. Viscosity
3. Color
4. Color stability
5. Cloud point
6. Clear point
7. pH
8. Fragrance
9. Sterility
10. Foam production = hard water , soft water , hard
water plus soil
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11. Foam stability
12. Speed of form production
13. Rinseability
14. Fragrance of lather
15. Combability of wet hair
16 .Combability of dry hair
17. Fragrance of the hair
18. Hair gloss
19. Static electricity of the hair
20. Effect on artificial hair color
21. Feel on hands
22. Staining of bleached or permanent waved hair
SKIN IRRITANT TEST :
PASS FAIL
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EYE IRRITANT TEST
PASS FAIL
• Microbiologicalassay:
• PREPARATIONOFPRE‐INOCULUM Take the loopful culture of
staphylococcusaureus (ATCC6532) aseptically and transfer to
sterilized and cooled 100ml SCDM (broth).
• Mixwell.Incubatethebrothat37oCfor24hrs.
• PREPARATIONOFMEDIA Soyabean casein digests medium,
soyabean casein digest agar and nutrient agar.
• PREPARATIONOFPOURPLATES SterilizedSCDagar (100ml) is cooled
to 40°C & mixed with 5ml of 24hr soldpreinoculatedculture.
• This is immediately poured inplates (340mleach) & allows to set.
• MAKINGTHEWELLSONAGARPLATEST he well saredigonagarplates
with sterilised well digger aseptically.
• Take 100μml of each sample, add to well aseptically.
Incubatetheplatesat 37oC for 24hrs to 48hrs.
• Observe the effectiveness of sample on culture growing on the
agarplate & wecan see the effectiveness of sample in the
formofzone of inhibition around each well containing different
sample.
SPECIFIC EXAMPLES
MARKETED SHAMPOO
❖ head & shoulders
❖ all clear
❖ garnier
❖ pantene
❖ dove
❖ sun silk
❖ cilinic plus
MEDICATED SHAMPOO:
❖ keshtone liquid shampoo
❖ kenazol shampoo
❖ alzirol ZPTO
❖ pyrithione shampoo
❖ nizoral anti – dandruff
❖ iodine shampoo ( animal )
❖ silver shampoo
REFERENCES
➢ balsam, s.m., gershon, s.d., rieger, m.m.,
COSMETIC SCIENCE AND TECHNOLOGY
➢ sharma, p.p COSMETIC
THANK YOU
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